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4. Degradation of Polymers Caused by Chemical Agents

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Aging of Polymers and Polymeric Materials Caused by Environmental Impact. Part 1

Table of contents

Preface. Aging and Stabilization of Polymers. Background

1. Macromolecular Reactions +

2. General Concepts in Aging of Polymers

3. Aging of Polymers Caused by Physical Factors +

4. Degradation of Polymers Caused by Chemical Agents -

4.1. Oxidative Destruction of Polymers

4.1.1. Mechanism of Auto-Oxidation of Polymers

4.1.2. Characteristics of Oxidation of Certain Types of Polymers

4.1.2.1. Specific Characteristics of Polybutadiene Oxidation

4.1.2.2. Specific Characteristics of 1,4-Polyisoprene Oxidation

4.1.2.3. Specific Characteristics of Polyethylene Oxidation

4.1.2.4. Specific Characteristics of Polypropylene Oxidation

4.1.2.5. Specific Characteristics of Polyamide Oxidation

4.1.2.6. Specific Characteristics of Polyurethane Oxidation

4.1.3. Photooxidation of Polymers

4.2. Destruction of Polymers Caused by Ozone

4.2.1. Ozone Aging of Rubbers

4.2.1.1. Factors Affecting the Rate of Ozone Aging

4.2.1.2. Classification of Rubbers according to Ozone Resistance

4.2.2. Photo-Ozone Aging

4.3. Combustion of Polymers

4.4. Degradation under the Influence of Chemically Active Agents of Various Nature

4.4.1. Hydrolytic Degradation of Polymers (Hydrolysis Reactions)

4.4.2. Degradation by exchange decomposition (Solvolysis reactions)

5. Biodegradation of Polymers +